Metal-intercalated aromatic hydrocarbons: a new class of carbon-based superconductors

被引：192

作者：

Kubozono, Yoshihiro ^{[1
,2
]}

Mitamura, Hiroki ^{[1
]}

Lee, Xuesong ^{[1
]}

He, Xuexia ^{[1
]}

Yamanari, Yusuke ^{[3
]}

Takahashi, Yosuke ^{[3
]}

Suzuki, Yuta ^{[3
]}

Kaji, Yumiko ^{[1
]}

Eguchi, Ritsuko ^{[1
]}

Akaike, Koki ^{[1
]}

Kambe, Takashi ^{[3
]}

Okamoto, Hideki ^{[4
]}

Fujiwara, Akihiko ^{[5
]}

Kato, Takashi ^{[6
]}

Kosugi, Taichi ^{[7
,8
]}

Aoki, Hideo ^{[7
]}

机构：

[1] Okayama Univ, Surface Sci Res Lab, Okayama 7008530, Japan

[2] Okayama Univ, Res Ctr New Funct Mat Energy Prod Transport & Sto, Okayama 7008530, Japan

[3] Okayama Univ, Dept Phys, Okayama 7008530, Japan

[4] Okayama Univ, Dept Chem & Biochem, Okayama 7008530, Japan

[5] Japan Synchrotron Radiat Res Inst, SPring 8, Sayocho, Hyogo 6795198, Japan

[6] Nagasaki Inst Appl Sci, Nagasaki 8510121, Japan

[7] Univ Tokyo, Dept Phys, Tokyo 1130033, Japan

[8] AIST, Nanosyst Res Inst, Tsukuba, Ibaraki 3058568, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2011年 / 13卷 / 37期

关键词：

THIN-FILMS; ELECTRICAL-PROPERTIES; ELECTRONIC-PROPERTIES; STRUCTURAL-ANALYSIS; GRAPHITE RIBBONS; STAGE STRUCTURE; PENTACENE; CS3C60; POLYMORPHISM; TEMPERATURE;

D O I：

10.1039/c1cp20961b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New carbon-based superconductors are synthesized by intercalating metal atoms into the solid-phase hydrocarbons picene and coronene. The highest reported superconducting transition temperature, T-c, of a hydrocarbon superconductor is 18 K for K(3)picene. The physics and chemistry of the hydrocarbon superconductors are extensively described for Axpicene (A: alkali and alkali earth-metal atoms) for x = 0-5. The theoretical picture of their electronic structure is also reviewed. Future prospects for hydrocarbon superconductors are discussed from the viewpoint of combining electronics with condensed-matter physics: modification of the physical properties of hydrocarbon solids is explored by building them into a field-effect transistor. The features of other carbon-based superconductors are compared to clarify the nature of hydrocarbon superconductors.

引用

页码：16476 / 16493

页数：18

共 107 条

[51] Ab initio electronic structure of solid coronene: Differences from and commonalities to picene [J].