Double stranded interwound infinite linear silver coordination network

被引：63

作者：

Schmaltz, B ^{[1
]}

Jouaiti, A ^{[1
]}

Hosseini, MW ^{[1
]}

De Cian, A ^{[1
]}

机构：

[1] Univ Strasbourg, Chim Coordinat Organ Lab, F-67000 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 14期

关键词：

D O I：

10.1039/b103824a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon self-assembly of a bismonodentate ligand based on two pyridine units interconnected at the para position by a hexaethylene glycol fragment using ester junctions and Ag+ cation, a double stranded interwound infinite linear network was obtained in the crystalline phase; the formation of this unprecedented architecture is a result of the loop type conformation of the connector segment which forms a pseudo-crown ether. The loop surounds the metal cation which is linearly coordinated to two pyridines belonging to consecutive units, thus forming the 1-D network.

引用

页码：1242 / 1243

页数：2

共 24 条

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