Bis-boranes in the frustrated Lewis pair activation of carbon dioxide

被引：104

作者：

Zhao, Xiaoxi ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 06期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CRYSTAL-STRUCTURES; COMPLEXES; CO2; HYDROGENATION; OPPORTUNITIES; B(C6F5)(3); CHALLENGES; REACTIVITY; CHEMISTRY; CATALYSTS;

D O I：

10.1039/c0cc04791k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a frustrated Lewis pair approach, the 1,1-bis-(C(6)F(5))(2)BOB(C(6)F(5))(2) is shown to bind CO(2) in a monodentate fashion, while the bis-boranes (X(2)B)(2)C=CMe(2) (X = Cl, C(6)F(5)) give bidentate chelation of CO(2) affording unique heterocycles.

引用

收藏

页码：1833 / 1835

页数：3

相关论文

共 28 条

[1] Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs [J].

Alcarazo, Manuel ;

Gomez, Catherine ;

Holle, Sigrid ;

Goddard, Richard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (33) :5788-5791

[2] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].

Arakawa, H ;

Aresta, M ;

Armor, JN ;

Barteau, MA ;

Beckman, EJ ;

Bell, AT ;

Bercaw, JE ;

Creutz, C ;

Dinjus, E ;

Dixon, DA ;

Domen, K ;

DuBois, DL ;

Eckert, J ;

Fujita, E ;

Gibson, DH ;

Goddard, WA ;

Goodman, DW ;

Keller, J ;

Kubas, GJ ;

Kung, HH ;

Lyons, JE ;

Manzer, LE ;

Marks, TJ ;

Morokuma, K ;

Nicholas, KM ;

Periana, R ;

Que, L ;

Rostrup-Nielson, J ;

Sachtler, WMH ;

Schmidt, LD ;

Sen, A ;

Somorjai, GA ;

Stair, PC ;

Stults, BR ;

Tumas, W .

CHEMICAL REVIEWS, 2001, 101 (04) :953-996

[3] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].

Aresta, Michele ;

Dibenedetto, Angela .

DALTON TRANSACTIONS, 2007, (28) :2975-2992

[4] Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH [J].

Ashley, Andrew E. ;

Thompson, Amber L. ;

O'Hare, Dermot .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9839-9843

[5] Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (31) :10660-10661

[6] Hydrogen and amine activation by a frustrated Lewis pair of a bulky n-heterocyclic carbene and B(C6F5)3 [J].

Chase, Preston A. ;

Stephan, Douglas W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (39) :7433-7437

[7] Carbon Dioxide Capture: Prospects for New Materials [J].

D'Alessandro, Deanna M. ;

Smit, Berend ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (35) :6058-6082

[8] Making plastics from carbon dioxide:: Salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2 [J].

Darensbourg, Donald J. .

CHEMICAL REVIEWS, 2007, 107 (06) :2388-2410

[9] Converting carbon dioxide into carbamato derivatives [J].

Dell'Amico, DB ;

Calderazzo, F ;

Labella, L ;

Marchetti, F ;

Pampaloni, G .

CHEMICAL REVIEWS, 2003, 103 (10) :3857-3897

[10] Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs [J].

Dureen, Meghan A. ;

Stephan, Douglas W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (24) :8396-+