Use of amino amides derived from proline as chiral ligands in the ruthenium(II)-catalyzed transfer hydrogenation reaction of ketones

被引：79

作者：

Rhyoo, HY

Yoon, YA

Park, HJ

Chung, YK ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea

[2] Seoul Natl Univ, Ctr Mol Catalysis, Seoul 151747, South Korea

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(01)00914-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We developed an efficient, easily available, and easy to use proline amide-based ruthenium(II) catalysts for the asymmetric hydride transfer reduction of prochiral ketones and e.e.s up to 98.8% have been measured. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5045 / 5048

页数：4

共 17 条

[1] Enantioselective reduction of aromatic ketones catalysed by chiral ruthenium(II) complexes
Aitali, M
Allaoud, S
Karim, A
Meliet, C
Mortreux, A
[J]. TETRAHEDRON-ASYMMETRY, 2000, 11 (06) : 1367 - 1374
[2] ALOSON DA, 2000, J ORG CHEM, V65, P3116
[3] SYNTHESIS AND CHARACTERIZATION OF NEW CHIRAL RH(I) COMPLEXES WITH N,N'-LIGANDS AND N,P-LIGANDS - A STUDY OF ANCHORING ON THE MODIFIED ZEOLITES AND CATALYTIC PROPERTIES OF HETEROGENIZED COMPLEXES
CARMONA, A
CORMA, A
IGLESIAS, M
SANJOSE, A
SANCHEZ, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 492 (01) : 11 - 21
[4] OPTICALLY-ACTIVE COMPLEXES OF TRANSITION-METALS (RH(I), RU(II), CO(II) AND NI(II)) WITH 2-AMINOCARBONYLPYRROLIDINE LIGANDS - SELECTIVE CATALYSTS FOR HYDROGENATION OF PROCHIRAL OLEFINS
CORMA, A
IGLESIAS, M
DELPINO, C
SANCHEZ, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 431 (02) : 233 - 246
[5] The catalyst precursor, catalyst, and intermediate in the Ru-II-promoted asymmetric hydrogen transfer between alcohols and ketones
Haack, KJ
Hashiguchi, S
Fujii, A
Ikariya, T
Noyori, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (03): : 285 - 288
[6] HASHIGUCHI S, 1997, ANGEW CHEM INT EDIT, V36, P88
[7] JAMES BR, 1997, CATAL TODAY, V37, P2095
[8] Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η6-p-cymene)Ru(amino acidato)Cl] and [(η6-p-cymene)Ru(amino acidato)]3(BF4)3 complexes
Kathó, A
Carmona, D
Viguri, F
Remacha, CD
Kovács, J
Joó, F
Oro, LA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 593 : 299 - 306
[9] Asymmetric transfer hydrogenation of alpha,beta-acetylenic ketones
Matsumura, K
Hashiguchi, S
Ikariya, T
Noyori, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (37) : 8738 - 8739
[10] ASYMMETRIC REDUCTION OF ACETOPHENONE WITH CHIRAL HYDRIDE REAGENT PREPARED FROM LITHIUM ALUMINUM-HYDRIDE AND (S)-2-(ANILINOMETHYL)PYRROLIDINE
MUKAIYAMA, T
ASAMI, M
HANNA, J
KOBAYASHI, S
[J]. CHEMISTRY LETTERS, 1977, (07) : 783 - 786

← 1 2 →