PdII-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands

被引：526

作者：

Shi, Bing-Feng ^{[1
]}

Maugel, Nathan ^{[2
]}

Zhang, Yang-Hui ^{[1
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[2] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 26期

关键词：

amino acids; boronic acids; C-C coupling; C-H activation; enantioselectivity;

D O I：

10.1002/anie.200801030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The relay of chiral information from the α-carbon atom of the amino acid ligand is believed to be crucial for chiral induction in the PdII-catalyzed enantioselective C-H activation/C-C coupling reaction of diphenyl(2-pyridyl)methane with boronic acids (see scheme; BQ=benzoquinone). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：4882 / 4886

页数：5

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