Effect of guest molecule flexibility in access to dendritic interiors

被引：26

作者：

Aathimanikandan, SV ^{[1
]}

Sandanaraj, BS

Arges, CG

Bardeen, CJ

Thayumanavan, S

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[2] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 14期

关键词：

D O I：

10.1021/ol050579b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dendrimers are attractive scaffolds for catalysis, since catalytic sites can be isolated and the catalysts are recoverable and reusable. Herein, we show that conformationally constrained molecules have better access to dendritic cores compared to the more flexible counterparts. The results reported here should have implications in utilizing dendrimers as scaffolds for artificial selectivity in catalysis.

引用

页码：2809 / 2812

页数：4

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