Dynamics of inherent structure in supercooled liquids near kinetic glass transition

被引:8
作者
Liao, CY [1 ]
Chen, SH [1 ]
机构
[1] MIT, Dept Nucl Engn, Cambridge, MA 02139 USA
来源
PHYSICAL REVIEW E | 2001年 / 64卷 / 03期
关键词
D O I
10.1103/PhysRevE.64.031202
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We present a description of the dynamics of a supercooled binary Lennard-Jones liquid in term of the potential landscape of the system. The slowing down of the dynamics in supercooled liquids near the kinetic glass transition is related to the existence of basins in the potential landscape. The inherent structures that are the local potential minima in the configuration space obtained by a quench process are employed to represent the configurations of the basins. We present time correlation functions of the inherent structure. both the self and the coherent part, as a function of wave vector. We also calculated the mean-square displacement, and the non-Gaussian parameter of the van Hove self-correlation function. Compared with the dynamics of original configurations. the short-time relaxation has almost been eliminated by the quench process. However, the long-time a relaxations remain essentially the same. We conclude that the long-time a relaxation is the result of cross-basin transition in the potential landscape in the configuration space.
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页数:6
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