Metal ligand aromatic cation-π interactions

被引：85

作者：

Zaric, SD

机构：

[1] Univ Belgrade, Dept Chem, YU-11001 Belgrade, Serbia

[2] Free Univ Berlin, Inst Chem, Dept Biol Chem & Pharm, D-14195 Berlin, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 12期

关键词：

chelates; density functional calculations; DNA; hydrogen bonds; metalloproteins; pi interactions; RNA;

D O I：

10.1002/ejic.200200278

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cation-pi interactions are important noncovalent bonding forces. This review covers a special type of cation-pi interactions, the metal ligand aromatic cation-pi (MLACpi) interaction, where ligands that are coordinated to a metal ion interact with aromatic groups. These interactions have been observed in metalloproteins, metal complexes, biomimetic metal complexes, and when DNA and RNA interact with metal cations. The energy of MLACpi interactions in different systems has been calculated by quantum chemical methods and Was found to vary from 1 to 30 kcal/mol. ((C) Wiley-VCH Verldg GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

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页码：2197 / 2209

页数：13

相关论文

共 157 条

[101]

NISHIO M, 1998, CHIPHI INTERACTION E

[102] Theoretical studies of inorganic and organometallic reaction mechanisms.: 14.: β-hydrogen transfer and alkene/alkyne insertion at a cationic iridium center [J].

Niu, SQ ;

Zaric, S ;

Bayse, CA ;

Strout, DL ;

Hall, MB .

ORGANOMETALLICS, 1998, 17 (23) :5139-5147

[103] Theoretical studies of inorganic and organometallic reaction mechanisms .11. Migratory insertion of coordinated nitric oxide into cobalt-carbon bonds [J].

Niu, SQ ;

Hall, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (13) :3077-3086

[104] Inter- and intramolecular C-H activation by a cationic iridium(III) center via oxidative-addition reductive-elimination and σ-bond metathesis pathways [J].

Niu, SQ ;

Hall, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (24) :6169-6170

[105] X-ray crystallographic studies of unique cross-linked lattices between four isomeric biantennary oligosaccharides and soybean agglutinin [J].

Olsen, LR ;

Dessen, A ;

Gupta, D ;

Sabesan, S ;

Sacchettini, JC ;

Brewer, CF .

BIOCHEMISTRY, 1997, 36 (49) :15073-15080

[106] CRYSTAL-STRUCTURE OF A 5-FINGER GLI-DNA COMPLEX - NEW PERSPECTIVES ON ZINC FINGERS [J].

PAVLETICH, NP ;

PABO, CO .

SCIENCE, 1993, 261 (5129) :1701-1707

[107] Water-mediated magnesium-guanine interactions [J].

Petrov, AS ;

Lamm, G ;

Pack, GR .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (12) :3294-3300

[108] The role of cation-π interactions in biomolecular association.: Design of peptides favoring interactions between cationic and aromatic amino acid side chains [J].

Pletneva, EV ;

Laederach, AT ;

Fulton, DB ;

Kostic, NM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) :6232-6245

[109]

Pulkkinen JT, 2000, J CHEM SOC P2, V2, P777

[110] STABILITY OF THE SILICON RUTHENIUM BOND IN THE PRESENCE OF A STRONG NUCLEOPHILE - PHASE-SENSITIVE H-1-NMR COSY AND CRYSTAL-STRUCTURE OF RU(CO)2(NH2CH2C6H5)2(SI(C6H5)(CH3)2)I [J].

RAPPOLI, BJ ;

MCGRATH, KJ ;

GEORGE, CF ;

COOPER, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 450 (1-2) :85-89

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