C60-based triads with improved electron-acceptor properties:: Pyrazolylpyrazolino[60]fullerenes

被引：55

作者：

Langa, F ^{[1
]}

de la Cruz, P

Espíldora, E

de la Hoz, A

Bourdelande, JL

Sánchez, L

Martín, N

机构：

[1] Univ Castilla La Mancha, Fac CC Medio Ambiente, Dept Q Organ, Toledo 45071, Spain

[2] Univ Castilla La Mancha, Fac CC Quim, Dept Q Organ, E-13071 Ciudad Real, Spain

[3] Univ Autonoma Barcelona, Dept Quim, Unitat Quim Organ, E-08913 Bellaterra, Spain

[4] Univ Complutense, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 15期

关键词：

D O I：

10.1021/jo001755r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of triad pyrazolylpyrazolino[60]fullerenes has been prepared in one pot from suitably functionalized hydrazones by 1,3-dipolar cycloaddition reactions under microwave irradiation. The electrochemical properties of the compounds obtained were investigated by cyclic voltammmetry, and they show better electron acceptor character than the parent C-60 in all cases. Fluorescence experiments and time-resolved transition spectroscopy indicate the existence of photoinduced charge-transfer processes with the C-60 triplet acting as the acceptor.

引用

页码：5033 / 5041

页数：9

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