Stripping potentiometry of indium in aqueous chloride solutions

被引:7
作者
Wilson, MM [1 ]
Dewald, HD [1 ]
机构
[1] Ohio Univ, Dept Chem & Biochem, Athens, OH 45701 USA
关键词
indium; stripping potentiometry; constant current;
D O I
10.1016/S0026-265X(00)00184-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Stripping potentiometry (SP) has been used effectively for the determination of trace levels of several metal species in solution. Indium ion, which can be readily reduced and has a high solubility in mercury, can be determined directly using SP. The reduction potential of indium is located between those of lead and cadmium, necessitating optimization of several experimental parameters for successful quantitative analysis. A method for the SP of In(III) is presented which utilizes constant current stripping analysis (CCSA) at a mercury-film glassy carbon electrode in KCI solutions in the presence of Pb(II) and Cd(II). (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:13 / 19
页数:7
相关论文
共 37 条
[21]   Determination of indium in bismuth indium telluride materials by anodic stripping voltammetry. Method development [J].
Kotrly, S ;
Pravda, M ;
Sramkova, J ;
Vytras, K .
ELECTROANALYSIS, 1996, 8 (8-9) :773-777
[22]   ANALYTICAL UTILITY OF THE IRIDIUM-BASED MERCURY ULTRAMICROELECTRODE WITH SQUARE-WAVE ANODIC-STRIPPING VOLTAMMETRY [J].
KOUNAVES, SP ;
DENG, W .
ANALYTICAL CHEMISTRY, 1993, 65 (04) :375-379
[23]   Indium as internal standard in square wave anodic stripping analysis of lead in blood with microelectrode arrays [J].
Liu, TZ ;
Lai, D ;
Osterloh, JD .
ANALYTICAL CHEMISTRY, 1997, 69 (17) :3539-3543
[24]  
LOSEV VV, 1976, ENCY ELECTROCHEMISTR, V6, pCH1
[25]   Electrodeposition of indium selenide In2Se3 [J].
Massaccesi, S ;
Sanchez, S ;
Vedel, J .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 412 (1-2) :95-101
[26]  
MEITERS L, 1983, HDB SERIES INORGANIC, V3, P248
[27]   POLAROGRAPHIC BEHAVIOR OF INDIUM IN PRESENCE OF CHLORIDE [J].
MOORHEAD, ED ;
MACNEVIN, WM .
ANALYTICAL CHEMISTRY, 1962, 34 (02) :269-&
[28]   Microfabricated array of iridium microdisks as a substrate for direct determination of Cu2+ or Hg2+ using square-wave anodic stripping voltammetry [J].
Nolan, MA ;
Kounaves, SP .
ANALYTICAL CHEMISTRY, 1999, 71 (16) :3567-3573
[29]   ELECTROCHEMISTRY OF INDIUM [J].
PIERCY, R ;
HAMPSON, NA .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1975, 5 (01) :1-15
[30]   EXTRACTIVE SEPARATION AND DETERMINATION OF THALLIUM AND INDIUM BY LIQUID SCINTILLATION-COUNTING [J].
RAJESH, N ;
SUBRAMANIAN, MS .
ANALYST, 1994, 119 (09) :2071-2074