Thin-films of poly-triarylamines for electro-optic applications

被引:6
作者
Choi, Kyungsun [1 ]
Kwak, Jeonghun [2 ]
Lee, Changhee [2 ]
Kim, Hosub [3 ,4 ]
Char, Kookheon [3 ,4 ]
Kim, Dong Young [5 ]
Zentel, Rudolf [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany
[2] Seoul Natl Univ, Sch Elect Engn & Comp Sci, Seoul 151744, South Korea
[3] Seoul Natl Univ, Inst Natl Core Res Ctr, Dept Chem & Biol Engn, Seoul 151744, South Korea
[4] Seoul Natl Univ, Inst Natl Core Res Ctr, NANO Syst, Seoul 151744, South Korea
[5] Korea Adv Inst Sci & Technol, Optoelect Mat Res Grp, Seoul 130650, South Korea
关键词
D O I
10.1007/s00289-007-0815-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We observed that a new anionic triarylamine copolymer, which is easily accessable by radical polymerization can be used for the preparation of thin semiconducting organic films in two extremely different ways: One is the LBL assembly from solution with a cationic polyelectrolyte as counter system; the other is direct vacuum deposition, whereby the polymer degrades to oligomers, but keeps the functional groups intact as proved by UV/Vis, NMR spectroscopy and cyclic voltammetry. The fabricated films are used in light emitting devices as hole transporting layers showing excellent properties. External EL quantum efficiency (eta(ext)) and luminous efficiency-current density (J) characteristics of PLED device were studied.
引用
收藏
页码:795 / 803
页数:9
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