An adamantane-based coordination framework with the first observation of discrete metal sulfonate clusters

被引：36

作者：

Hoffart, DJ ^{[1
]}

Côté, AP ^{[1
]}

Shimizu, GKH ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 26期

关键词：

D O I：

10.1021/ic0349398

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By employing a rigid adamantane-based unit as a spacer, a coordination solid with an open channel layered structure results showing the first observation of metal sulfonate clusters. The design approach employed enforces a structural mismatch of metal and ligand coordinative preferences.

引用

页码：8603 / 8605

页数：3

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