Reactivity of stable trifluoroacetaldehyde hemiaminals. I. An unexpected reaction with enolizable carbonyl compounds

被引：42

作者：

Blond, G ^{[1
]}

Billard, T ^{[1
]}

Langlois, BR ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, UMR 5622, Lab SERCOF, F-69622 Villeurbanne, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 14期

关键词：

D O I：

10.1021/jo015587u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of enolizable carbonyl compounds, hemiaminals of fluoral and related polyfluoro-aldehydes behave as equivalents of fluoroalkyl iminium compounds and provide beta -polyfluoroalkyl beta -dialkylamino ketones, which are easily transformed, under acidic conditions, into beta -polyfluoroalkylenones.

引用

页码：4826 / 4830

页数：5

共 18 条

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