Tuning metalloporphyrin and metallophthalocyanine redox potentials using ligand electrochemical (EL) and Hammett (σP) parametrization

被引：41

作者：

Alexiou, C ^{[1
]}

Lever, ABP ^{[1
]}

机构：

[1] York Univ, Dept Chem, Toronto, ON M3J 1P3, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 216卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

metalloporphyrins; metallophthalocyanines; ligand electrochemical parameter; Hammett parameter;

D O I：

10.1016/S0010-8545(01)00350-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A compilation and analysis of literature values for a number of iron and chromium tetraphenylporphyrins shows that there is a linear correlation between observed M-III II potentials and the total contribution of the axial ligand electrochemical parameters, SigmaE(L)(L). Substituted iron and chromium phthalocyanine adducts in different coordinating solvents indicate that the potential of the M-II III odor couple is linearly dependent on SigmaE(L)(L) and on the total Hammett para substituent constant, Sigma sigma (p). The application of this electrochemical model to the design of metallomacrocycles possessing desired values of E,, is discussed, (C) 2001 Elsevier Science B.V. AH rights reserved.

引用

页码：45 / 54

页数：10

共 91 条

[31]

HANACK M, 1992, COMMUNICATION

[32] A SURVEY OF HAMMETT SUBSTITUENT CONSTANTS AND RESONANCE AND FIELD PARAMETERS [J].