[(C2H5)3NH]2Cu2(C2O4)3: a three-dimensional metal-oxalato framework showing structurally related dielectric and magnetic transitions at around 165 K

被引：36

作者：

Zhang, Bin ^{[1
,2
]}

Zhang, Yan ^{[3
]}

Zhu, Daoben ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, BNLMS, Organ Solid Lab, CMS, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China

[3] Peking Univ, Dept Phys, Inst Condensed Matter & Mat Phys, Beijing 100871, Peoples R China

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 28期

基金：

美国国家科学基金会;

关键词：

COEXISTENCE; COMPOUND; CATIONS; CHAINS;

D O I：

10.1039/c2dt30818e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An achiral (10,3) net three-dimensional metal-oxalato framework [Cu-2(C2O4)(3)(2-)](n) was formed by cation-templating. At around 165 K, the disorder-order transition of cation (C2H5)(3)NH+ hosted in the channel resulted in dielectric transition, and the antiferromagnetic interactions between the Jahn-Teller distorted Cu(II) through the oxalato-bridge below 165 K was enhanced.

引用

页码：8509 / 8511

页数：3

共 26 条

[21] Disorder-Order Ferroelectric Transition in the Metal Formate Framework of [NH4][Zn(HCOO)3] [J].

Xu, Guan-Cheng ;

Ma, Xiao-Ming ;

Zhang, Li ;

Wang, Zhe-Ming ;

Gao, Song .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (28) :9588-9590

[22] Synthesis, structure, and magnetic properties of (A)[FeIII(oxalate)Cl2] (A = alkyl ammonium cations) with anionic 1D [FeIII(oxalate)Cl2]- chains [J].

Xu, Hong-Bin ;

Wang, Zhe-Ming ;

Liu, Tao ;

Gao, Song .

INORGANIC CHEMISTRY, 2007, 46 (08) :3089-3096

[23] A neutral molecular-based layered magnet [Fe(C2O4)(CH3OH)]n exhibiting magnetic ordering at TN≈23 K [J].

Zhang, Bin ;

Zhang, Yan ;

Zhang, Jinbiao ;

Lia, Junchao ;

Zhu, Daoben .

DALTON TRANSACTIONS, 2008, (37) :5037-5040

[24] Guest-induced chirality in the ferrimagnetic nanoporous diamond framework Mn3(HCOO)6 [J].

Zhang, Bin ;

Wang, Zheming ;

Kurmoo, Mohamedally ;

Gao, Song ;

Inoue, Katsuya ;

Kobayashi, Hayao .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (04) :577-584

[25] (BEDT-TTF)3Cu2(C2O4)3(CH3OH)2: an organic-inorganic hybrid antiferromagnetic semiconductor [J].

Zhang, Bin ;

Zhang, Yan ;

Zhu, Daoben .

CHEMICAL COMMUNICATIONS, 2012, 48 (02) :197-199

[26] Mn(C2O4)(H2O)0.25: an antiferromagnetic oxalato-based cage compound [J].

Zhang, Bin ;

Zhang, Yan ;

Zhang, Jinbiao ;

Hao, Xiang ;

Zhu, Daoben .

DALTON TRANSACTIONS, 2011, 40 (20) :5430-5432

← 1 2 3 →