Synthesis, solution dynamics, and x-ray crystal structure of bis(2,4,6-tris(trifluoromethyl)phenyl)(1,2-dimethoxyethane)nickel

被引：14

作者：

Benedikt, GM

Goodall, BL

Iyer, S

McIntosh, LH

Mimna, R

Rhodes, LF

Day, CS

Day, VW

机构：

[1] BF Goodrich Co, Brecksville, OH 44141 USA

[2] Crystalyt Co, Lincoln, NE 68501 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 12期

关键词：

D O I：

10.1021/om0100784

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of dichloro(1,2-dimethoxyethane)nickel with 2 equiv of(tris(2, 4,6-trifluoromethyl)-phenyl)lithium, generated in situ, produced bis(2,4,6-tris(trifluoromethyl)phenyl)(1,2- dimethoxyethane)nickel. Significant nickel-fluorine interactions are revealed both in the solid state (X-ray crystal structure data) and in solution (variable-temperature F-19 NMR spectral data).

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页码：2565 / 2569

页数：5

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