Rechargeable alkali-ion cathode-flow battery

We provide a proof of concept of a lithium battery configuration containing an aqueous cathode in a flow-through mode. A room-temperature, rechargeable alkali-ion battery with a commercially available Li(+)-ion solid-electrolyte separating a Li(0) anode and an organic liquid-carbonate electrolyte on one side and, on the other, an aqueous cathode containing 0.1 M K(3)Fe(CN)(6) has been demonstrated to give high efficiency electrical energy storage at 3.40 V; it is capable of matching the capacity of the Li(0) anode if operated with the aqueous cathode in a flow-through mode. The resistance of the solid electrolyte rather than the flow rate of the cathode determined the power density of the test cell. The concept can be used with a more-abundant Na(0) anode and a Na(+)-ion solid electrolyte. The results call for the development of an alkali-ion solid-electrolyte separator with a smaller resistance.