A review of recent results on electrochemical determination of the density of electronic states of nanostructured metal-oxide semiconductors and organic hole conductors

被引:278
作者
Bisquert, Juan [1 ]
Fabregat-Santiago, Francisco [1 ]
Mora-Sero, Ivan [1 ]
Garcia-Belmonte, Germa [1 ]
Barea, Eva M. [1 ]
Palomares, Emilio [2 ]
机构
[1] Univ Jaume 1, Dept Fis, Castellon de La Plana 12071, Spain
[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
关键词
dye solar cell; nanostructured semiconductor; organic conductor; impedance spectroscopy;
D O I
10.1016/j.ica.2007.05.032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The paper reviews recent results on electrochemical methods applied to the determination of the density of electronic states in several components of advanced nanostructured devices such as the dye solar cell (Gratzel cell), switchable displays, and sensors. We discuss the application of cyclic voltammetry and impedance spectroscopy to determine the chemical capacitance of mesoporous metal-oxide semiconductors (mainly TiO2), organic hole transport materials, and molecular functionalizing elements. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:684 / 698
页数:15
相关论文
共 93 条
  • [41] Photoelectrochemical cells
    Grätzel, M
    [J]. NATURE, 2001, 414 (6861) : 338 - 344
  • [42] Materials science -: Ultrafast colour displays
    Grätzel, M
    [J]. NATURE, 2001, 409 (6820) : 575 - 576
  • [43] LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS
    HAGFELDT, A
    GRATZEL, M
    [J]. CHEMICAL REVIEWS, 1995, 95 (01) : 49 - 68
  • [44] Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells
    Hauch, A
    Georg, A
    [J]. ELECTROCHIMICA ACTA, 2001, 46 (22) : 3457 - 3466
  • [45] Impedance analysis for dye-sensitized solar cells with a reference electrode
    Hoshikawa, T
    Kikuchi, R
    Eguchi, K
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2006, 588 (01) : 59 - 67
  • [46] Orbital occupation in electron-charged CdSe quantum-dot solids
    Houtepen, AJ
    Vanmaekelbergh, D
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (42) : 19634 - 19642
  • [47] Wide energy-window view on the density of states and hole mobility in poly(p-phenylene vinylene) -: art. no. 166601
    Hulea, IN
    Brom, HB
    Houtepen, AJ
    Vanmaekelbergh, D
    Kelly, JJ
    Meulenkamp, EA
    [J]. PHYSICAL REVIEW LETTERS, 2004, 93 (16) : 166601 - 1
  • [48] Generalised equivalent circuits for mass and charge transport: chemical capacitance and its implications
    Jamnik, J
    Maier, J
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (09) : 1668 - 1678
  • [49] STUDY OF NANOCRYSTALLINE TIO2 (ANATASE) ELECTRODE IN THE ACCUMULATION REGIME
    KAVAN, L
    KRATOCHVILOVA, K
    GRATZEL, M
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 394 (1-2): : 93 - 102
  • [50] Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions
    Kern, R
    Sastrawan, R
    Ferber, J
    Stangl, R
    Luther, J
    [J]. ELECTROCHIMICA ACTA, 2002, 47 (26) : 4213 - 4225