Immobilized baker's yeast reduction of ketones in an ionic liquid, [bmim]PF6 and water mix

被引：147

作者：

Howarth, J ^{[1
]}

James, P ^{[1
]}

Dai, JF ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 42期

关键词：

baker's yeast; ionic liquid; reduction;

D O I：

10.1016/S0040-4039(01)01601-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bioreduction with immobilized baker's yeast of several ketones was carried out in a 10:1 [bmim]PF6 ionic liquid:water mix. The reductions produced alcohols with comparable enantioselectivities to baker's yeast reductions in alternative media. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：7517 / 7519

页数：3

相关论文

共 26 条

[1] ABSOLUTE CONFIGURATION OF ALPHA- AND BETA-METHYLCHOLINE ISOMERS AND THEIR ACETYL AND SUCCINYL ESTERS [J].

BECKETT, AH ;

CLITHEROW, JW ;

HARPER, NJ .

JOURNAL OF PHARMACY AND PHARMACOLOGY, 1963, 15 (06) :349-&

[2] The Heck reaction in ionic liquids: A multiphasic catalyst system [J].

Carmichael, AJ ;

Earle, MJ ;

Holbrey, JD ;

McCormac, PB ;

Seddon, KR .

ORGANIC LETTERS, 1999, 1 (07) :997-1000

[3]

Cull SG, 2000, BIOTECHNOL BIOENG, V69, P227

[4] Regioselective alkylation in ionic liquids [J].

Earle, MJ ;

McCormac, PB ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 1998, (20) :2245-2246

[5] Enzymatic catalysis of formation of Z-aspartame in ionic liquid -: An alternative to enzymatic catalysis in organic solvents [J].

Erbeldinger, M ;

Mesiano, AJ ;

Russell, AJ .

BIOTECHNOLOGY PROGRESS, 2000, 16 (06) :1129-1131

[6] USE OF BIOLOGICAL-SYSTEMS FOR THE SYNTHESIS OF CHIRAL MOLECULES .5. MICROBIOLOGICAL REDUCTION OF ACYCLIC BETA-DIKETONES [J].

FAUVE, A ;

VESCHAMBRE, H .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (22) :5215-5219

[7] The coupling of aryl halides in the ionic liquid [bmim]PF6 [J].

Howarth, J ;

James, P ;

Dai, JF .

TETRAHEDRON LETTERS, 2000, 41 (52) :10319-10321

[8] Moisture stable ambient temperature ionic liquids: Solvents for the new millennium. 1. The heck reaction [J].

Howarth, J ;

Dallas, A .

MOLECULES, 2000, 5 (06) :851-855

[9] Oxidation of aromatic aldehydes in the ionic liquid [bmim]PF6 [J].

Howarth, J .

TETRAHEDRON LETTERS, 2000, 41 (34) :6627-6629

[10]

HOWARTH J, 2001, SYNTHETIC COMMUN, V31, P51