Formation of pyrrolidines by the titanocene(II)-promoted intramolecular reaction of N-[3,3-bis(phenylthio)propyl]anilides

被引：14

作者：

Takeda, T ^{[1
]}

Saito, J ^{[1
]}

Tsubouchi, A ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Koganei, Tokyo 1848588, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(03)01385-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of anilides with the titanium carbene complexes generated by the desulfurization of thioacetals with the titanocene(II) species CP2Ti[P(OEt)(3)](2) produced the corresponding enamines. Unusual formation of pyrrolidines was observed when N-[3,3 - bis(phenylthio)propyl]anilides were treated with the titanocene(II) reagent. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：5571 / 5574

页数：4

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