Effective combination of nonthermal plasma and catalysts for decomposition of benzene in air

被引:106
作者
Ogata, A [1 ]
Einaga, H [1 ]
Kabashima, H [1 ]
Futamura, S [1 ]
Kushiyama, S [1 ]
Kim, HH [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, AIST Tsukuba W, Tsukuba, Ibaraki 3058569, Japan
关键词
nonthermal plasma; catalyst; adsorbent; benzene; decomposition; activation; BaTiO3; zeolite;
D O I
10.1016/S0926-3373(03)00180-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effective combination of plasma energy and solid surface properties, such as catalysis and adsorption, was investigated using packed-bed type catalyst-hybrid and adsorbent-hybrid reactors that were packed with a mixture of BaTiO3 pellets and other ceramic pellets (catalyst or adsorbent). The plasma reactor that employed catalysts indicated improvement in CO2 selectivity and suppression of N2O formation compared with the reactor that was packed with BaTiO3 alone. It was also found that the catalysts and adsorbents in the plasma reactor were useful in enhancing energy efficiency. Furthermore, the catalyst and adsorbent positions in the plasma reactor were very important for induction of surface reactions on the packed materials. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:87 / 95
页数:9
相关论文
共 18 条
[1]  
Clothiaux E. J., 1984, Plasma Chemistry and Plasma Processing, V4, P15, DOI 10.1007/BF00567368
[2]   Cleaning of air streams from organic pollutants by plasma-catalytic oxidation [J].
Francke, KP ;
Miessner, H ;
Rudolph, R .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 2000, 20 (03) :393-403
[3]  
HARA N, 1975, ZEOLITES BASIS APPL
[4]   Combination of non-thermal plasma and heterogeneous catalysis for oxidation of volatile organic compounds Part 1. Accessibility of the intra-particle volume [J].
Holzer, F ;
Roland, U ;
Kopinke, FD .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 38 (03) :163-181
[5]   Destruction of volatile organic compounds used in a semiconductor industry by a capillary tube discharge reactor [J].
Kohno, H ;
Berezin, AA ;
Chang, JS ;
Tamura, M ;
Yamamoto, T ;
Shibuya, A ;
Hondo, S .
IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, 1998, 34 (05) :953-966
[6]   Decomposition of toluene by streamer corona discharge with catalyst [J].
Li, DA ;
Yakushiji, D ;
Kanazawa, S ;
Ohkubo, T ;
Nomoto, Y .
JOURNAL OF ELECTROSTATICS, 2002, 55 (3-4) :311-319
[7]   Plasma-enhanced HC-SCR of NOx in the presence of excess oxygen [J].
Miessner, H ;
Francke, KP ;
Rudolph, R .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 36 (01) :53-62
[8]   LOW-TEMPERATURE ATMOSPHERIC-PRESSURE DISCHARGE PLASMA PROCESSING FOR VOLATILE ORGANIC-COMPOUNDS [J].
ODA, T ;
KUMADA, A ;
TANAKA, K ;
TAKAHASHI, T ;
MASUDA, S .
JOURNAL OF ELECTROSTATICS, 1995, 35 (01) :93-101
[9]   Oxidation of dilute benzene ire an alumina hybrid plasma reactor at atmospheric pressure [J].
Ogata, A ;
Yamanouchi, K ;
Mizuno, K ;
Kushiyama, S ;
Yamamoto, T .
PLASMA CHEMISTRY AND PLASMA PROCESSING, 1999, 19 (03) :383-394
[10]   Decomposition of benzene using a nonthermal plasma reactor packed with ferroelectric pellets [J].
Ogata, A ;
Shintani, N ;
Mizuno, K ;
Kushiyama, S ;
Yamamoto, T .
IEEE TRANSACTIONS ON INDUSTRY APPLICATIONS, 1999, 35 (04) :753-759