Semiconductor-enriched single wall carbon nanotube networks applied to field effect transistors

被引:126
作者
Izard, N. [1 ]
Kazaoui, S. [1 ]
Hata, K. [1 ]
Okazaki, T. [1 ]
Saito, T. [1 ]
Iijima, S. [1 ]
Minami, N. [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba 3058565, Japan
基金
日本学术振兴会;
关键词
D O I
10.1063/1.2939560
中图分类号
O59 [应用物理学];
学科分类号
摘要
Substantial progress on field effect transistors (FETs) consisting of semiconducting single wall carbon nanotubes (s-SWNTs) without detectable traces of metallic nanotubes and impurities is reported. Nearly perfect removal of metallic nanotubes is confirmed by optical absorption, Raman measurements, and electrical measurements. This outstanding result was made possible in particular by ultracentrifugation (150 000 g) of solutions prepared from SWNT powders using polyfluorene as an extracting agent in toluene. Such s-SWNTs processable solutions were applied to realize FET, embodying randomly or preferentially oriented nanotube networks prepared by spin coating or dielectrophoresis. Devices exhibit stable p-type semiconductor behavior in air with very promising characteristics. The on-off current ratio is 10(5), the on-current level is around 10 mu A, and the estimated hole mobility is larger than 2 cm(2)/V s.
引用
收藏
页数:3
相关论文
共 18 条
[1]   Sorting carbon nanotubes by electronic structure using density differentiation [J].
Arnold, Michael S. ;
Green, Alexander A. ;
Hulvat, James F. ;
Stupp, Samuel I. ;
Hersam, Mark C. .
NATURE NANOTECHNOLOGY, 2006, 1 (01) :60-65
[2]   Nanotube electronics and optoelectronics [J].
Avouris, Phaedon ;
Chen, Jia .
MATERIALS TODAY, 2006, 9 (10) :46-54
[3]  
BIERCUK MJ, 2008, CARBON NANOTUBES ADV
[4]   Toward the extraction of single species of sinale-walled carbon nanotubes using fluorene-based polymers [J].
Chen, Fuming ;
Wang, Bo ;
Chen, Yuan ;
Li, Lain-Jong .
NANO LETTERS, 2007, 7 (10) :3013-3017
[5]   Solution-processed single-walled carbon nanotube transistors with high mobility and large on/off ratio [J].
Fukao, Tomohiro ;
Nakamura, Shuichi ;
Kataura, Hiromichi ;
Shiraishi, Masashi .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (8A) :6524-6527
[6]   Displays develop a new flexibility [J].
Jang, Jin .
MATERIALS TODAY, 2006, 9 (04) :46-52
[7]   High-performance electronics using dense, perfectly aligned arrays of single-walled carbon nanotubes [J].
Kang, Seong Jun ;
Kocabas, Coskun ;
Ozel, Taner ;
Shim, Moonsub ;
Pimparkar, Ninad ;
Alam, Muhammad A. ;
Rotkin, Slava V. ;
Rogers, John A. .
NATURE NANOTECHNOLOGY, 2007, 2 (04) :230-236
[8]   Intrinsic current gain cutoff frequency of 30 GHz with carbon nanotube transistors [J].
Le Louarn, A. ;
Kapche, F. ;
Bethoux, J.-M. ;
Happy, H. ;
Dambrine, G. ;
Derycke, V. ;
Chenevier, P. ;
Izard, N. ;
Goffman, M. F. ;
Bourgoin, J.-P. ;
Derycke, V. ;
Chenevier, P. ;
Izard, N. ;
Goffman, M. F. ;
Bourgoin, J.-P. .
APPLIED PHYSICS LETTERS, 2007, 90 (23)
[9]   Large-scale separation of metallic and semiconducting single-walled carbon nanotubes [J].
Maeda, Y ;
Kimura, S ;
Kanda, M ;
Hirashima, Y ;
Hasegawa, T ;
Wakahara, T ;
Lian, YF ;
Nakahodo, T ;
Tsuchiya, T ;
Akasaka, T ;
Lu, J ;
Zhang, XW ;
Gao, ZX ;
Yu, YP ;
Nagase, S ;
Kazaoui, S ;
Minami, N ;
Shimizu, T ;
Tokumoto, H ;
Saito, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (29) :10287-10290
[10]   Separation of semiconducting from metallic carbon nanotubes by selective functionalization with azomethine ylides [J].
Menard-Moyon, Cecilia ;
Izard, Nicolas ;
Doris, Eric ;
Mioskowski, Charles .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (20) :6552-6553