Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk

被引：391

作者：

Hadjichristidis, N

Iatrou, H

Pitsikalis, M

Pispas, S

Avgeropoulos, A

机构：

[1] Univ Athens, Dept Chem, Athens 15771, Greece

[2] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[3] Univ Ioannina, Dept Mat Sci & Engn, GR-45110 Ioannina, Greece

来源：

PROGRESS IN POLYMER SCIENCE | 2005年 / 30卷 / 07期

关键词：

triblock terpolymers; linear; miktoarm star; cyclic; synthesis; living polymerization; living/controlled polymerizations; self-assembly; selective solvents; bulk;

D O I：

10.1016/j.progpolymsci.2005.04.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of linear and non-linear (star, cyclic) triblock terpolymers through living, controlled/living polymerization methods and their combinations are reviewed. The theoretical predictions and the experimental results concerning the self-assembly of these materials in selective solvents and in bulk are also discussed. A plethora of self-assembled structures have been detected either in solution or in bulk, potentially leading to a rich variety of high-tech applications. First results regarding the synthesis and morphology of multicomponent multiblock (tetrablock quarter and pentablock quinto) polymers are also given. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：725 / 782

页数：58

共 128 条

[51]

Hamley I., 1998, The Physics of Block Copolymers Oxford University Press

[52] Synthesis of ABC 3-miktoarm star terpolymers from a trifunctional initiator by combining ring-opening polymerization, atom transfer radical polymerization, and nitroxide-mediated radical polymerization [J].