Linear and non-linear triblock terpolymers. Synthesis, self-assembly in selective solvents and in bulk

被引：389

作者：

Hadjichristidis, N

Iatrou, H

Pitsikalis, M

Pispas, S

Avgeropoulos, A

机构：

[1] Univ Athens, Dept Chem, Athens 15771, Greece

[2] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[3] Univ Ioannina, Dept Mat Sci & Engn, GR-45110 Ioannina, Greece

来源：

PROGRESS IN POLYMER SCIENCE | 2005年 / 30卷 / 07期

关键词：

triblock terpolymers; linear; miktoarm star; cyclic; synthesis; living polymerization; living/controlled polymerizations; self-assembly; selective solvents; bulk;

D O I：

10.1016/j.progpolymsci.2005.04.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of linear and non-linear (star, cyclic) triblock terpolymers through living, controlled/living polymerization methods and their combinations are reviewed. The theoretical predictions and the experimental results concerning the self-assembly of these materials in selective solvents and in bulk are also discussed. A plethora of self-assembled structures have been detected either in solution or in bulk, potentially leading to a rich variety of high-tech applications. First results regarding the synthesis and morphology of multicomponent multiblock (tetrablock quarter and pentablock quinto) polymers are also given. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：725 / 782

页数：58

共 128 条

[21] Synthesis of shell cross-linked micelles at high solids in aqueous media [J].

Bütün, V ;

Wang, XS ;

Báñez, MVD ;

Robinson, KL ;

Billingham, NC ;

Armes, SP ;

Tuzar, Z .

MACROMOLECULES, 2000, 33 (01) :1-3

[22] A Zwitterionic ABC triblock copolymer that forms a "Trinity" of micellar aggregates in aqueous solution [J].

Cai, YL ;

Armes, SP .

MACROMOLECULES, 2004, 37 (19) :7116-7122

[23] Synthesis of miktoarm star and miktoarm star block copolymers via a combination of atom transfer radical polymerization and stable free-radical polymerization [J].

Celik, C ;

Hizal, G ;

Tunca, U .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (16) :2542-2548

[24] EFFECT OF BLOCK SIZE AND SEQUENCE ON THE MICELLIZATION OF ABC TRIBLOCK METHACRYLIC POLYAMPHOLYTES [J].

CHEN, WY ;

ALEXANDRIDIS, P ;

SU, CK ;

PATRICKIOS, CS ;

HERTLER, WR ;

HATTON, TA .

MACROMOLECULES, 1995, 28 (25) :8604-8611

[25] Design of ABC triblock copolymers near the ODT with the random phase approximation [J].

Cochran, EW ;

Morse, DC ;

Bates, FS .

MACROMOLECULES, 2003, 36 (03) :782-792

[26] PROPERTIES OF BLOCK COPOLYMERS AND HOMOPOLYMER BLENDS COMPRISED OF 1,2-POLYBUTADIENE AND 1,4-POLYBUTADIENE [J].

COHEN, RE ;

WILFONG, DE .

MACROMOLECULES, 1982, 15 (02) :370-375

[27] HOMOGENEOUS AND HETEROGENEOUS BLENDS OF POLYBUTADIENE, POLYISOPRENE, AND CORRESPONDING DIBLOCK COPOLYMERS [J].

COHEN, RE ;

RAMOS, AR .

MACROMOLECULES, 1979, 12 (01) :131-134

[28] ABC triblock copolymers prepared using atom transfer radical polymerization techniques [J].

Davis, KA ;

Matyjaszewski, K .

MACROMOLECULES, 2001, 34 (07) :2101-2107

[29] Complex spherical micelles in A-B-C-block copolymer melts [J].

Dormidontova, EE ;

Khokhlov, AR .

MACROMOLECULES, 1997, 30 (07) :1980-1991

[30] Synthesis of model linear tetrablock quaterpolymers and pentablock quintopolymers of ethylene oxide [J].

Ekizoglou, N ;

Hadjichristidis, N .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (13) :2166-2170

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