Structural direction by the dominant metal

被引：34

作者：

Beswick, MA ^{[1
]}

Mosquera, MEG ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a800687c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Assessment of the structures of a number of heterometallic alkali metal/p block metal complexes suggests that the p block metals have a dominant role in dictating the structures of these species, since generally greater covalency of the metal-ligand interactions leads to more geometrically rigid metal co-ordination.

引用

页码：2437 / 2443

页数：7

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