Structural determination of metallofuIlerene SC3C82 revisited:: A surprising finding

被引：194

作者：

Iiduka, Y

Wakahara, T

Nakahodo, T

Tsuchiya, T

Sakuraba, A

Maeda, Y

Akasaka, T ^{[1
]}

Yoza, K

Horn, E

Kato, T

Liu, MTH

Mizorogi, N

Kobayashi, K

Nagase, S

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[3] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[4] Bruker AXS KK, Yokohama, Kanagawa 2210022, Japan

[5] Rikkyo Univ, Dept Chem, Tokyo 1718501, Japan

[6] Josai Univ, Dept Chem, Sakado, Saitama 3500295, Japan

[7] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada

[8] Inst Mol Sci, Dept Theoret Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 36期

关键词：

D O I：

10.1021/ja054209u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here the structural determination of the Sc3C82 molecule by 13C NMR spectroscopy and X-ray single-crystal structure analysis. From the present study, it is obvious that the structure of Sc3C82is not Sc3@C82 but Sc3C2@C80. Copyright © 2005 American Chemical Society.

引用

页码：12500 / 12501

页数：2

共 35 条

[11] ESR STUDY ON STRUCTURES AND DYNAMICS OF SC-3-AT-C-82 [J].