Intramolecular reaction of gamma-alkoxyallylstannane with hydrazone: Stereoselective synthesis of beta-aminotetrahydro-pyran and -furan

被引：12

作者：

Kadota, I ^{[1
]}

Park, JY ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acid mediated cyclization of gamma-oxygen substituted allylic stannanes 1, 2 and 9, bearing a hydrazone group at the terminus of the carbon chain, afforded the corresponding trans-beta-amino cyclic ethers 3a, 4a and 10, respectively, with very high diastereoselectivities in high chemical yields.

引用

页码：841 / 842

页数：2

共 15 条

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[15] YAMAMOTO Y, 1994, MAIN GROUP MET CHEM, V17, P269

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