Well-defined graft copolymers: from controlled synthesis to multipurpose applications

被引：416

作者：

Feng, Chun ^{[1
,2
]}

Li, Yongjun ^{[1
,2
]}

Yang, Dong ^{[3
,4
]}

Hu, Jianhua ^{[3
,4
]}

Zhang, Xiaohuan ^{[3
,4
]}

Huang, Xiaoyu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Lab Polymer Mat, Shanghai 200032, Peoples R China

[3] Fudan Univ, Adv Mat Lab, Minist Educ, Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China

[4] Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 03期

基金：

中国国家自然科学基金;

关键词：

TRANSFER RADICAL POLYMERIZATION; CYLINDRICAL MOLECULAR BRUSHES; RING-OPENING METATHESIS; ONE-POT SYNTHESIS; SIDE-CHAINS; BLOCK-COPOLYMERS; COUPLING CHEMISTRY; TANDEM CATALYSIS; CLICK CHEMISTRY; SOFT ELASTOMERS;

D O I：

10.1039/b921358a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Graft copolymers with a large number of side chains chemically attached onto a linear backbone are endowed with unusual properties thanks to their confined and compact structures, including wormlike conformation, compact molecular dimensions and notable chain end effects. Growing attention has been paid to these interesting macromolecules due to their importance in understanding the correlation between architectures and properties, as well as their potential applications. To date, the synthesis and properties of graft copolymers in both solution and bulk have been extensively investigated, along with their applications. In this tutorial review, recent advances in synthetic approaches towards the construction of well-defined graft copolymers are discussed in detail and applications of these interesting macromolecules are highlighted by selected examples.

引用

页码：1282 / 1295

页数：14

共 68 条

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