ROMP from ROMP: A New Approach to Graft Copolymer Synthesis

被引：37

作者：

Allen, Matthew J. ^{[1
]}

Wangkanont, Kittikhun ^{[1
]}

Raines, Ronald T. ^{[1
,2
]}

Kiessling, Laura L. ^{[1
,2
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Univ Wisconsin, Dept Biochem, Madison, WI 53706 USA

来源：

MACROMOLECULES | 2009年 / 42卷 / 12期

关键词：

RING-OPENING-METATHESIS; TRANSFER RADICAL POLYMERIZATION; COMB BLOCK-COPOLYMERS; CYLINDRICAL BRUSHES; ONE-POT; POLYMERS; ROUTE; CORE; ATRP; COMBINATION;

D O I：

10.1021/ma900056b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

A new strategy is presented for the synthesis of graft copolymers using only the ring-opening metathesis polymerization (ROMP). From a ROMP-derived main chain, pendant maleimide functional groups are converted into norbornene moieties via a Diels-Alder reaction with cyclopentadiene. The norbornene groups serve as sites of initiation, and subsequent ROMP from the main chain yields graft copolymers with both main and side chains derived from ROMP. This strategy offers ready access to defined graft copolymers.

引用

收藏

页码：4023 / 4027

页数：5

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