Isomerically pure electron-deficient anthradithiophenes and their acceptor performance in polymer solar cells

被引:35
作者
Li, Zhong [1 ]
Lim, Yee-Fun [2 ]
Kim, Jong Bok [3 ]
Parkin, Sean R. [1 ]
Loo, Yueh-Lin [3 ]
Malliaras, George G. [2 ,4 ]
Anthony, John E. [1 ]
机构
[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
[2] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14850 USA
[3] Princeton Univ, Dept Chem & Biol Engn, Princeton, NJ 08544 USA
[4] Ecole Natl Super Mines, Ctr Microelect Provence, F-13541 Gardanne, France
基金
美国国家科学基金会;
关键词
FIELD-EFFECT TRANSISTORS; PHOTOVOLTAIC CELLS; EFFICIENT; PENTACENE; 2-VINYL-4,5-DICYANOIMIDAZOLES; DERIVATIVES;
D O I
10.1039/c1cc12410b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amide functionalized anthradithiophenes (ADTs) play active acceptor roles in polymer bulk-heterojunction solar cells. The first separation of ADT isomers is reported, and the regio-chemistry of the ADT has significant impact on crystal packing and solar cell performance. Cell efficiency up to 0.80%, due in large part to high open-circuit voltage (V-OC > 1.0 V), is achieved in bulk-heterojunction solar cells comprising syn-ADT and poly(3-hexylthiophene).
引用
收藏
页码:7617 / 7619
页数:3
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