Ruthenium(IV) alkylidenes as precatalysts for direct arylations of Alkenes with aryl chlorides and an application to sequential catalysis

被引：140

作者：

Ackermann, Lutz ^{[1
]}

Born, Robert ^{[1
]}

Alvarez-Bercedo, Paula ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 33期

关键词：

alkenes; C-H activation; hydrosilylation; ruthenium carbenes; sequential catalysis;

D O I：

10.1002/anie.200701727

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Jack of all trades? A ruthenium(IV) carbene complex catalyzes the diastereoselective direct arylation of alkenes using aryl chlorides with high efficiency, which sets the stage for the development of a direct arylation-hydrosilylation sequence (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6364 / 6367

页数：4

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