Palladacyclic catalysts in C-C and C-heteroatom bond-forming reactions

被引:471
作者
Bedford, RB [1 ]
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
关键词
D O I
10.1039/b211298c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Palladacycles are amongst the most active catalysts in Heck-type carbon - carbon bond formation and related carbon-heteroatom bond forming reactions. For instance they have recently emerged as showing the highest activity in the Suzuki coupling of electronically challenging aryl chloride substrates. In addition to the high activity they display, their ease of synthesis, facile modification and comparative stability all act to enhance their appeal.
引用
收藏
页码:1787 / 1796
页数:10
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共 82 条
[31]  
Dupont J, 2001, EUR J INORG CHEM, P1917
[32]  
Dyker G, 1999, ANGEW CHEM INT EDIT, V38, P1699, DOI 10.1002/(SICI)1521-3773(19990614)38:12<1698::AID-ANIE1698>3.0.CO
[33]  
2-6
[34]   Pyrazole and benzothiazole palladacycles: stable and efficient catalysts for carbon-carbon bond formation [J].
Gai, XJ ;
Grigg, R ;
Ramzan, MI ;
Sridharan, V ;
Collard, S ;
Muir, JE .
CHEMICAL COMMUNICATIONS, 2000, (20) :2053-2054
[35]   Highly efficient C-C coupling reactions using metallated benzylphosphine complexes of palladium [J].
Gibson, S ;
Foster, DF ;
Eastham, GR ;
Tooze, RP ;
Cole-Hamilton, DJ .
CHEMICAL COMMUNICATIONS, 2001, (08) :779-780
[36]   Introduction: Recoverable catalysts and reagents - Perspective and prospective [J].
Gladysz, JA .
CHEMICAL REVIEWS, 2002, 102 (10) :3215-3216
[37]   TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES [J].
GRUSHIN, VV ;
ALPER, H .
CHEMICAL REVIEWS, 1994, 94 (04) :1047-1062
[38]  
Guari Y, 1999, EUR J INORG CHEM, P1047
[39]   Palladacycles: Efficient new catalysts for the Heck vinylation of aryl halides [J].
Herrmann, WA ;
Brossmer, C ;
Reisinger, CP ;
Riermeier, TH ;
Ofele, K ;
Beller, M .
CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) :1357-1364
[40]   PALLADACYCLES AS STRUCTURALLY DEFINED CATALYSTS FOR THE HECK OLEFINATION OF CHLOROARENES AND BROMOARENES [J].
HERRMANN, WA ;
BROSSMER, C ;
OFELE, K ;
REISINGER, CP ;
PRIERMEIER, T ;
BELLER, M ;
FISCHER, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1844-1848