Electropolymerized Pd-containing thiophene polymer: A reusable supported catalyst for cross-coupling reactions

被引:25
作者
Albano, Vincenzo G.
Bandini, Marco
Moorlag, Carolyn
Piccinelli, Fabio
Pietrangelo, Agostino
Tommasi, Simona
Umani-Ronchi, Achille
Wolf, Michael O.
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
关键词
D O I
10.1021/om070210l
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Electrodeposition of Pd-containing oligothienyl complexes on porous graphite electrodes allows the preparation of a new, reusable heterogeneous organometallic catalyst for intra-as well as intermolecular cross-coupling reactions.
引用
收藏
页码:4373 / 4375
页数:3
相关论文
共 31 条
[1]   Controlling stereochemical outcomes of asymmetric processes by catalyst remote molecular functionalizations: Chiral diamino-oligothiophenes (DATs) as ligands in asymmetric catalysis [J].
Albano, VG ;
Bandini, M ;
Barbarella, G ;
Melucci, M ;
Monari, M ;
Piccinelli, F ;
Tommasi, S ;
Umani-Ronchi, A .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (03) :667-675
[2]   Novel chiral diamino-oligothiophenes as valuable ligands in Pd-catalyzed allylic alkylations. On the "primary" role of "secondary" interactions in asymmetric catalysis [J].
Albano, VG ;
Bandini, M ;
Melucci, M ;
Monari, M ;
Piccinelli, F ;
Tommasi, S ;
Umani-Ronchi, A .
ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (11-13) :1507-1512
[3]  
[Anonymous], 2001, FINE CHEM HETEROGENE
[4]  
[Anonymous], 1979, HDB XRAY PHOTOELECTR
[5]   Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes [J].
Bandini, Marco ;
Piccinelli, Fabio ;
Tommasi, Simona ;
Umani-Ronchi, Achille ;
Ventrici, Caterina .
CHEMICAL COMMUNICATIONS, 2007, (06) :616-618
[6]   The heck reaction as a sharpening stone of palladium catalysis [J].
Beletskaya, IP ;
Cheprakov, AV .
CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066
[7]   Supported palladium catalysts for fine chemicals synthesis [J].
Blaser, HU ;
Indolese, A ;
Schnyder, A ;
Steiner, H ;
Studer, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) :3-18
[8]   Palladium complexes with chiral oxazoline ligands.: Effect of chelate size on catalytic allylic substitutions [J].
Canal, JM ;
Gómez, M ;
Jiménez, F ;
Rocamora, M ;
Muller, G ;
Duñach, E ;
Franco, D ;
Jiménez, A ;
Cano, FH .
ORGANOMETALLICS, 2000, 19 (06) :966-978
[9]   Electropolymerization of a cyclometalated terthiophene: A hybrid material with a palladium-carbon bond to the backbone [J].
Clot, O ;
Wolf, MO ;
Patrick, BO .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (42) :10456-10457
[10]   Electropolymerization of Pd(II) complexes containing phosphinoterthiophene ligands [J].
Clot, O ;
Wolf, MO ;
Patrick, BO .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :9963-9973