A new alternative to Stryker's reagent in hydrosilylation: synthesis, structure, and reactivity of a well-defined carbene-copper(II) acetate complex

被引：64

作者：

Yun, J ^{[1
]}

Kim, D

Yun, H

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Inst Basic Sci, Suwon 440746, South Korea

[3] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 41期

关键词：

D O I：

10.1039/b509964a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new, air stable and well-defined carbene -copper(II) complex has been prepared, which is an efficient precatalyst for the 1,2and 1,4-reduction of carbonyl compounds under hydrosilylation conditions.

引用

页码：5181 / 5183

页数：3

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