Research Update: Strategies for improving the stability of perovskite solar cells

被引:129
作者
Habisreutinger, Severin N. [1 ]
McMeekin, David P. [1 ]
Snaith, Henry J. [1 ]
Nicholas, Robin J. [1 ]
机构
[1] Univ Oxford, Dept Phys, Clarendon Lab, Parks Rd, Oxford OX1 3PU, England
来源
APL MATERIALS | 2016年 / 4卷 / 09期
基金
英国工程与自然科学研究理事会;
关键词
HOLE TRANSPORT MATERIALS; HIGH-PERFORMANCE; CH3NH3PBI3; PEROVSKITE; LEAD TRIHALIDE; HALIDE PEROVSKITES; INTERFACIAL LAYER; COLLECTION LAYER; HIGHLY EFFICIENT; BLOCKING LAYER; CONDUCTOR-FREE;
D O I
10.1063/1.4961210
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The power-conversion efficiency of perovskite solar cells has soared up to 22.1% earlier this year. Within merely five years, the perovskite solar cell can now compete on efficiency with inorganic thin-film technologies, making it the most promising of the new, emerging photovoltaic solar cell technologies. The next grand challenge is now the aspect of stability. The hydrophilicity and volatility of the organic methylammonium makes the work-horse material methylammonium lead iodide vulnerable to degradation through humidity and heat. Additionally, ultraviolet radiation and oxygen constitute stressors which can deteriorate the device performance. There are two fundamental strategies to increasing the device stability: developing protective layers around the vulnerable perovskite absorber and developing a more resilient perovskite absorber. The most important reports in literature are summarized and analyzed here, letting us conclude that any long-term stability, on par with that of inorganic thin-film technologies, is only possible with a more resilient perovskite incorporated in a highly protective device design. (C) 2016 Author(s).
引用
收藏
页数:15
相关论文
共 136 条
[1]   Silolothiophene-linked triphenylamines as stable hole transporting materials for high efficiency perovskite solar cells [J].
Abate, Antonio ;
Paek, Sanghyun ;
Giordano, Fabrizio ;
Correa-Baena, Juan-Pablo ;
Saliba, Michael ;
Gao, Peng ;
Matsui, Taisuke ;
Ko, Jaejung ;
Zakeeruddin, Shaik M. ;
Dahmen, Klaus H. ;
Hagfeldt, Anders ;
Graetzel, Michael ;
Nazeeruddin, Mohammad Khaja .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (10) :2946-2953
[2]  
[Anonymous], ENERGY ENV SCI
[3]   The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers [J].
Aristidou, Nicholas ;
Sanchez-Molina, Irene ;
Chotchuangchutchaval, Thana ;
Brown, Michael ;
Martinez, Luis ;
Rath, Thomas ;
Haque, Saif A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (28) :8208-8212
[4]   Achieving long-term stable perovskite solar cells via ion neutralization [J].
Back, Hyungcheol ;
Kim, Geunjin ;
Kim, Junghwan ;
Kong, Jaemin ;
Kim, Tae Kyun ;
Kang, Hongkyu ;
Kim, Heejoo ;
Lee, Jinho ;
Lee, Seongyu ;
Lee, Kwanghee .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (04) :1258-1263
[5]   Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].
Baikie, Tom ;
Fang, Yanan ;
Kadro, Jeannette M. ;
Schreyer, Martin ;
Wei, Fengxia ;
Mhaisalkar, Subodh G. ;
Graetzel, Michael ;
White, Tim J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641
[6]   Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells [J].
Beal, Rachel E. ;
Slotcavage, Daniel J. ;
Leijtens, Tomas ;
Bowring, Andrea R. ;
Belisle, Rebecca A. ;
Nguyen, William H. ;
Burkhard, George F. ;
Hoke, Eric T. ;
McGehee, Michael D. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (05) :746-751
[7]   Organometal halide perovskite solar cells: degradation and stability [J].
Berhe, Taame Abraha ;
Su, Wei-Nien ;
Chen, Ching-Hsiang ;
Pan, Chun-Jern ;
Cheng, Ju-Hsiang ;
Chen, Hung-Ming ;
Tsai, Meng-Che ;
Chen, Liang-Yih ;
Dubale, Amare Aregahegn ;
Hwang, Bing-Joe .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (02) :323-356
[8]   Efficient luminescent solar cells based on tailored mixed-cation perovskites [J].
Bi, Dongqin ;
Tress, Wolfgang ;
Dar, M. Ibrahim ;
Gao, Peng ;
Luo, Jingshan ;
Renevier, Clementine ;
Schenk, Kurt ;
Abate, Antonio ;
Giordano, Fabrizio ;
Baena, Juan-Pablo Correa ;
Decoppet, Jean-David ;
Zakeeruddin, Shaik Mohammed ;
Nazeeruddin, Mohammad Khaja ;
Gratzel, Michael ;
Hagfeldt, Anders .
SCIENCE ADVANCES, 2016, 2 (01)
[9]   Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells [J].
Bi, Dongqin ;
Boschloo, Gerrit ;
Schwarzmueller, Stefan ;
Yang, Lei ;
Johansson, Erik M. J. ;
Hagfeldt, Anders .
NANOSCALE, 2013, 5 (23) :11686-11691
[10]   Stabilization of the Trigonal High-Temperature Phase of Formamidinium Lead Iodide [J].
Binek, Andreas ;
Hanusch, Fabian C. ;
Docampo, Pablo ;
Bein, Thomas .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (07) :1249-1253