Helicate self-assembly from heterotopic ligand strands of specific binding site sequence

被引：94

作者：

Smith, VCM ^{[1
]}

Lehn, JM ^{[1
]}

机构：

[1] INST LE BEL,URA 422,LAB CHIM SUPRAMOL,F-67000 STRASBOURG,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 24期

关键词：

D O I：

10.1039/cc9960002733

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linear ligands containing a sequence of three bipyridine B and terpyridine T units form homo- or hetero-nuclear duplex helicates with Cu-I, Cu-II and Fe-II ions; of particular interest is the case of a [(BTB)(CuCuCuII)-Cu-II-Cu-II(TBT)] combination which amounts to the translation of one strand into the other one by virtue of the B-T correspondence established by the five-coordinate Cu-II ions.

引用

页码：2733 / 2734

页数：2

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