Synthesis and X-ray crystal structure of a benzannelated diazabutadiene (DAB) complex of gallium

被引:8
作者
Brown, DS [1 ]
Decken, A [1 ]
Cowley, AH [1 ]
机构
[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712
关键词
D O I
10.1016/0277-5387(96)00166-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first benzannelated diazabutadiene complex of gallium, C6H4(NSiMe(3))(2)GaR (3; R = 2-(dimethylaminomethyl)phenyl), has been prepared by treatment of C6H4(N(Li)SiMe(3))(2) with RGaCl(2). Compound 3 has been characterized both spectroscopically and by means of X-ray crystallography. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:4109 / 4112
页数:4
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