Gold molecular precursors and gold-silica interactions

被引：34

作者：

Abis, L

Armelao, L

Dell'Amico, DB

Calderazzo, F

Garbassi, F

Merigo, A

Quadrelli, EA

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[2] EniChem CR Novara Ist Guido Donegani, I-28100 Novara, Italy

[3] Univ Padua, Dipartimento Chim Inorgan Metallorgan & Analit, CNR, CSSRCC, I-35135 Padua, Italy

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b103414f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The gold(I) precursor Au(O2CNEt2)(PPh3) has been successfully employed to graft isolated Au(PPh3) fragments on amorphous silica. Molecular models of the silica surface. i.e. Ph3SiOH, (c-C5H9)(7)Si7O12SiOH and (c-C5H9)(7)Si7O9(OH)(3), have been found to react with Au(O2CNR2)(PPh3), R = Me, Et, yielding the corresponding silanolato molecular complexes containing the SiO-Au(PPh3) moiety. Gold nanoparticles on silica have been produced by using AuCl(CO) as precursor.

引用

页码：2704 / 2709

页数：6

共 63 条

[31]

Frisch M.J., 1995, GAUSSIAN 94

[32] Gold nanoparticles from self-assembled gold(I) amine precursors [J].