Direct structural evidences of Mn11Ge8 and Mn5Ge2 clusters in Ge0.96Mn0.04 thin films

被引:62
作者
Wang, Yong [1 ,2 ]
Zou, Jin [1 ,2 ]
Zhao, Zuoming [3 ]
Han, Xinhai [3 ]
Zhou, Xiaoyu [3 ]
Wang, Kang L. [3 ]
机构
[1] Univ Queensland, Sch Engn, Brisbane, Qld 4072, Australia
[2] Univ Queensland, Ctr Microscopy & Microanal, Brisbane, Qld 4072, Australia
[3] Univ Calif Los Angeles, Dept Elect Engn, Los Angeles, CA 90095 USA
关键词
D O I
10.1063/1.2884527
中图分类号
O59 [应用物理学];
学科分类号
摘要
Mn-rich clusters in Mn-doped Ge thin films epitaxially grown on Ge (001) have been investigated by various transmission electron microscopy techniques. Both the mysterious Mn11Ge8 and the hexagonal Mn5Ge2 (a=0.72 nm and c=1.3 nm) clusters were confirmed to coexist in the thicker Ge0.96Mn0.04 film (80 nm). Their possible formation mechanism is attributed to the existence of ordered stacking faults. The fact that no Mn-rich clusters found in thinner films (<=40 nm) suggests that, for a given Mn concentration and growth/annealing condition, a critical thickness exists for the formation of Mn-rich clusters. (C) 2008 American Institute of Physics.
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页数:3
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