Titanium(IV) imido complexes of 1,3,5-trialkyl-1,3,5-triazacyclohexanes

被引：12

作者：

Baker, MV ^{[1
]}

Palermo, MC ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 03期

关键词：

D O I：

10.1071/C98173

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of the imido complex Ti(NBut)Cl-2(py)(3) (py = pyridine) with 1,3,5-trialkyl-1,3,5-triazacyclohexanes (R(3)tach) produce the corresponding imido complexes TiCl2(NBut)(R(3)tach) (R = Et, Bu-t). The new complexes have been characterized by n.m.r. spectroscopy and, for the R = Bu-t case, by X-ray diffraction studies. The absence of a C-3 upsilon axis of symmetry for the new complexes allowed complete and unequivocal assignment of their H-1 n.m.r. spectra by consideration of proton-proton coupling and nuclear Overhauser erects.

引用

页码：179 / 183

页数：5

共 18 条

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