Microstructure and electronic investigations of carbon nitride films deposited by RF magnetron sputtering

被引:18
作者
Lagrini, A
Charvet, S
Benlahsen, M
Debiemme-Chouvy, C
Deslouis, C
Cachet, H
机构
[1] UPRES, EA 2081, Phys Mat Condensee Lab, Fac Sci Amiens, F-80039 Amiens, France
[2] Univ Paris 06, UPR 15, CNRS, LISE, F-75252 Paris, France
关键词
carbon; nitrides; sputtering; Raman spectroscopy;
D O I
10.1016/j.tsf.2004.11.154
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The analysis of the relationship between the local microstructure evolution versus nitrogen content and electrical properties of amorphous carbon nitride films (a-CNx) deposited by radio frequency (RF) magnetron sputtering is reported. Combined TRIM code, XPS measurements and Raman scattering spectroscopy are used to investigate the microstructure of a-CNx, films, in their as-deposited state, in terms of surface processes, nitrogen incorporation within the films and the Csp(2) content. These experiments were completed by dark electrical conductivity measurements performed at room temperature in coplanar configuration. A good correlation is observed between the local microstructure and the conductivity at different amounts of nitrogen. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:41 / 44
页数:4
相关论文
共 20 条
[1]   The electrochemical reactivity of amorphous hydrogenated carbon nitrides for varying nitrogen contents: the role of the substrate [J].
Adamopoulos, G ;
Godet, C ;
Deslouis, C ;
Cachet, H ;
Lagrini, A ;
Saidani, B .
DIAMOND AND RELATED MATERIALS, 2003, 12 (3-7) :613-617
[2]   MODELING STUDIES OF AMORPHOUS-CARBON [J].
BEEMAN, D ;
SILVERMAN, J ;
LYNDS, R ;
ANDERSON, MR .
PHYSICAL REVIEW B, 1984, 30 (02) :870-875
[3]   Electrochemistry of nitrogen-incorporated hydrogenated amorphous carbon films [J].
Cachet, H ;
Deslouis, C ;
Chouiki, M ;
Saidani, B ;
Conway, NMJ ;
Godet, C .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (07) :E233-E241
[4]   Electron transfer kinetics on composite diamond (sp3)-graphite (sp2) electrodes [J].
Duo, I ;
Fujishima, A ;
Comninellis, CH .
ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (08) :695-700
[5]   Deposition mechanism of sputtered amorphous carbon nitride thin film [J].
Durand-Drouhin, O ;
Benlahsen, M ;
Clin, M ;
Bouzerar, R .
APPLIED SURFACE SCIENCE, 2004, 223 (04) :269-274
[6]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[7]   Interpretation of infrared and Raman spectra of amorphous carbon nitrides [J].
Ferrari, AC ;
Rodil, SE ;
Robertson, J .
PHYSICAL REVIEW B, 2003, 67 (15)
[8]   Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2001, 64 (07)
[9]   Effect of chemical sputtering on the growth and structural evolution of magnetron sputtered CNx thin films [J].
Hellgren, N ;
Johansson, MP ;
Broitman, E ;
Sandström, P ;
Hultman, L ;
Sundgren, JE .
THIN SOLID FILMS, 2001, 382 (1-2) :146-152
[10]  
HULTMAN L, 2003, MRS BULL, P194