Nucleophilic addition of triethyl phosphite to acetates of the Baylis-Hillman adducts: Stereoselective synthesis of (E)- and (Z)-allylphosphonates

被引：43

作者：

Basavaiah, D

Pandiaraju, S

机构：

[1] School of Chemistry, University of Hyderabad

来源：

TETRAHEDRON | 1996年 / 52卷 / 06期

关键词：

D O I：

10.1016/0040-4020(95)01055-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nucleophilic addition of triethyl phosphite to 3-acetoxy-2-methylenealkanenitriles and methyl 3-acetoxy-2-methylenealkanoates provides (2E)-2-(diethoxyphosphorylmethyl)alk-2-enenitriles and methyl (2Z)-2-(diethoxyphosphorylmethyl) alk-2-enoates respectively with good stereoselectivity.

引用

页码：2261 / 2268

页数：8

共 16 条

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