Diphosphites as a promising new class of ligands in Pd-catalysed asymmetric allylic alkylation

被引：50

作者：

Diéguez, M

Jansat, S

Gomez, M

Ruiz, A

Muller, G

Claver, C

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 12期

关键词：

D O I：

10.1039/b101567m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of diphosphite ligands, derived from readily available D-(+)-glucose, have been used for the first time in the palladium-catalysed allylic alkylation reaction with high enantioselectivity (ee up to 95%) and activity in standard conditions.

引用

页码：1132 / 1133

页数：2

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