Highly effective NPN-type tridentate ligands for asymmetric transfer hydrogenation of ketones

被引：117

作者：

Jiang, YT ^{[1
]}

Jiang, QZ ^{[1
]}

Zhu, GX ^{[1
]}

Zhang, XM ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIVERSITY PK,PA 16802

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(96)02257-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New chiral NPN-type tridentate ligands containing two oxazoline rings and one phosphine have been synthesized, and their Ru(II) complexes show high reactivity and enantioselectivity in transfer hydrogenations of both aryl alkyl and dialkyl ketones (with ee's up to 92% for a dialkyl ketone). Copyright (C) 1996 Elsevier Science Ltd

引用

页码：215 / 218

页数：4

共 15 条

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