Ionic liquid-graphene composite for ultratrace explosive trinitrotoluene detection

被引:119
作者
Guo, Chun Xian [1 ,2 ]
Lu, Zhi Song [1 ,2 ]
Lei, Yu [3 ]
Li, Chang Ming [1 ,2 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
[2] Nanyang Technol Univ, Ctr Adv Bionanosyst, Singapore 637457, Singapore
[3] Univ Connecticut, Dept Chem Mat & Biomol Engn, Storrs, CT 06269 USA
关键词
Ionic liquid; Graphene; Three-dimensional structure; Explosive detection; Trinitrotoluene; NITROAROMATIC COMPOUNDS; DIRECT ELECTROCHEMISTRY; CARBON; ELECTRODE; HEMOGLOBIN; BIOSENSOR; SENSOR;
D O I
10.1016/j.elecom.2010.06.028
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A new ionic liquid (IL)-graphene composite prepared by combining IL and a three-dimensional graphene material with large specific surface area and pronounced mesoporosity was used for ultratrace trinitrotoluene detection, showing low background current, high sensitivity of 1.65 mu A cm(-2) per ppb, low detection limit of 0.5 ppb and good reproducibility, which is much superior to that demonstrated by the IL-CNT and IL-graphite composites. The preparation of IL-graphene composite expands the scope of IL-based electrochemical devices. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1237 / 1240
页数:4
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