Determination of the Local Chemical Structure of Graphene Oxide and Reduced Graphene Oxide

被引：1060

作者：

Erickson, Kris ^{[1
]}

Erni, Rolf ^{[2
,3
]}

Lee, Zonghoon ^{[2
]}

Alem, Nasim ^{[1
]}

Gannett, Will ^{[1
]}

Zettl, Alex ^{[1
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Natl Ctr Elect Microscopy, Berkeley, CA 94720 USA

[3] Empa Swiss Fed Labs Mat Testing & Res, CH-8600 Dubendorf, Switzerland

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 40期

基金：

美国国家科学基金会;

关键词：

GRAPHITE OXIDE; FILMS; TRANSPARENT; MONOLAYERS; MOLECULES; DYNAMICS; SHEETS; VAPOR; ORDER;

D O I：

10.1002/adma.201000732

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The local atomic structure of graphene oxide (GO) and reduced annealed graphene oxide (raGO) is determined via ultra-high-resolution transmission electron microscopy. We find that the proposed and desired return to graphene from GO is not possible through the synthetic route employed. The detailed structure of GO, previously unknown, is revealed as mottled, with few square nanometer graphitic regions separated by highly oxidized regions. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4467 / 4472

页数：6

共 36 条

[1] A study of the reaction of oxygen with graphite: Model chemistry [J].

Backreedy, R ;

Jones, JM ;

Pourkashanian, M ;

Williams, A .

FARADAY DISCUSSIONS, 2001, 119 :385-394

[2] Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].

Becerril, Hdctor A. ;

Mao, Jie ;

Liu, Zunfeng ;

Stoltenberg, Randall M. ;

Bao, Zhenan ;

Chen, Yongsheng .

ACS NANO, 2008, 2 (03) :463-470

[3] Electronic confinement and coherence in patterned epitaxial graphene [J].

Berger, Claire ;

Song, Zhimin ;

Li, Xuebin ;

Wu, Xiaosong ;

Brown, Nate ;

Naud, Cecile ;

Mayou, Didier ;

Li, Tianbo ;

Hass, Joanna ;

Marchenkov, Atexei N. ;

Conrad, Edward H. ;

First, Phillip N. ;

de Heer, Wait A. .

SCIENCE, 2006, 312 (5777) :1191-1196

[4] A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons [J].

Brenner, DW ;

Shenderova, OA ;

Harrison, JA ;

Stuart, SJ ;

Ni, B ;

Sinnott, SB .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (04) :783-802

[5] Synthesis and solid-state NMR structural characterization of 13C-labeled graphite oxide [J].

Cai, Weiwei ;

Piner, Richard D. ;

Stadermann, Frank J. ;

Park, Sungjin ;

Shaibat, Medhat A. ;

Ishii, Yoshitaka ;

Yang, Dongxing ;

Velamakanni, Aruna ;

An, Sung Jin ;

Stoller, Meryl ;

An, Jinho ;

Chen, Dongmin ;

Ruoff, Rodney S. .

SCIENCE, 2008, 321 (5897) :1815-1817

[6] Mechanically strong, electrically conductive, and biocompatible graphene paper [J].

Chen, Haiqun ;

Mueller, Marc B. ;

Gilmore, Kerry J. ;

Wallace, Gordon G. ;

Li, Dan .

ADVANCED MATERIALS, 2008, 20 (18) :3557-+

[7] Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material [J].

Eda, Goki ;

Fanchini, Giovanni ;

Chhowalla, Manish .

NATURE NANOTECHNOLOGY, 2008, 3 (05) :270-274

[8] Beam-induced damage to thin specimens in an intense electron probe [J].

Egerton, RF ;

Wang, F ;

Crozier, PA .

MICROSCOPY AND MICROANALYSIS, 2006, 12 (01) :65-71

[9] Graphene at the Edge: Stability and Dynamics [J].

Girit, Caglar Oe ;

Meyer, Jannik C. ;

Erni, Rolf ;

Rossell, Marta D. ;

Kisielowski, C. ;

Yang, Li ;

Park, Cheol-Hwan ;

Crommie, M. F. ;

Cohen, Marvin L. ;

Louie, Steven G. ;

Zettl, A. .

SCIENCE, 2009, 323 (5922) :1705-1708

[10] Atomic Structure of Reduced Graphene Oxide [J].

Gomez-Navarro, Cristina ;

Meyer, Jannik C. ;

Sundaram, Ravi S. ;

Chuvilin, Andrey ;

Kurasch, Simon ;

Burghard, Marko ;

Kern, Klaus ;

Kaiser, Ute .

NANO LETTERS, 2010, 10 (04) :1144-1148

← 1 2 3 4 →