An unusual three-dimensional coordination network formed by parallel polycatenation of two-fold interpenetrated (6,3) layers based on a novel three-connecting ligand

被引：43

作者：

Banfi, S

Carlucci, L

Caruso, E

Ciani, G ^{[1
]}

Proserpio, DM

机构：

[1] Univ Insubria, Dipartimento Biol Strutturale & Funz, Via JH Dunant 3, I-21100 Varese, Italy

[2] Univ Milan, Dipartimento Chim Strutt & Shereochim Inorgan, I-20133 Milan, Italy

来源：

CRYSTAL GROWTH & DESIGN | 2004年 / 4卷 / 01期

关键词：

D O I：

10.1021/cg0341454

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6-trimethylbenzene (1) together with silver(1) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)].0.5H(2)O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.

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页码：29 / 32

页数：4

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