An unusual three-dimensional coordination network formed by parallel polycatenation of two-fold interpenetrated (6,3) layers based on a novel three-connecting ligand

被引:43
作者
Banfi, S
Carlucci, L
Caruso, E
Ciani, G [1 ]
Proserpio, DM
机构
[1] Univ Insubria, Dipartimento Biol Strutturale & Funz, Via JH Dunant 3, I-21100 Varese, Italy
[2] Univ Milan, Dipartimento Chim Strutt & Shereochim Inorgan, I-20133 Milan, Italy
关键词
D O I
10.1021/cg0341454
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6-trimethylbenzene (1) together with silver(1) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)].0.5H(2)O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.
引用
收藏
页码:29 / 32
页数:4
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