Inorganic-organometallic crystal synthesis.: The role of charge-assisted C-H...O and C-H...Cl hydrogen bonds in crystalline [(η5-C5H5)2Co][H2PO4]•3H2O and [(η6-C6H5Me)2Cr][Cl]

被引：47

作者：

Braga, D

Draper, SM

Champeil, E

Grepioni, F

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 573卷 / 1-2期

关键词：

cobaltocenium salts; hydrogen bonding; structural analysis;

D O I：

10.1016/S0022-328X(98)00620-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organometallic dihydrogen phosphate [(eta(5)-C5H5)(2)Co][H2PO4]. 3H(2)O has been obtained by direct reaction of phosphoric acid with the organometallic hydroxide [(eta(5)-C5H5)(2)Co][OH] prepared in situ by oxidation of [(eta(5)-C5H5)(2)Co] in water. The role of negatively charged O-H ... O(-) and neutral O-H ... O hydrogen bonds between the H2PO4- anions and water molecules and that of charge-assisted C-Hdelta+ ... Odelta- hydrogen-bonds between organometallic and inorganic components has been investigated. The crystal structure of the chloride [(eta(6)-C6H5Me)(2)Cr][Cl] has also been used to analyse charge assisted C-Hdelta+ ... Cl- interactions. The results have been compared with data retrieved from the Cambridge Crystallographic Database. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：73 / 77

页数：5

共 17 条

[1] A NOVEL CLASS OF SALTS FOR 2ND HARMONIC-GENERATION
AAKEROY, CB
HITCHCOCK, PB
MOYLE, BD
SEDDON, KR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) : 1856 - 1859
[2] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
ALLEN, FH
DAVIES, JE
GALLOY, JJ
JOHNSON, O
KENNARD, O
MACRAE, CF
MITCHELL, EM
MITCHELL, GF
SMITH, JM
WATSON, DG
[J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
[3] ALLEN FH, 1991, J CHEM INF COMP SCI, V31, P204
[4] AULLON G, 1998, IN PRESS CHEM COMMUN
[5] FROM MOLECULE TO MOLECULAR AGGREGATION - CLUSTERS AND CRYSTALS OF CLUSTERS
BRAGA, D
GREPIONI, F
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (02) : 51 - 56
[6] Organic-organometallic crystal synthesis .1. Hosting paramagnetic [(eta(6)-arene)(2)Cr](+) (arene equals benzene, toluene) in organic anion frameworks via O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds
Braga, D
Costa, AL
Grepioni, F
Scaccianoce, L
Tagliavini, E
[J]. ORGANOMETALLICS, 1997, 16 (10) : 2070 - 2079
[7] OH-O and CH-O hydrogen bonding in hydrated crystals of paramagnetic [(eta(6)-C6H6)(2)Cr](+)
Braga, D
Costa, AL
Grepioni, F
Scaccianoce, L
Tagliavini, E
[J]. ORGANOMETALLICS, 1996, 15 (04) : 1084 - 1086
[8] HOSTING PARAMAGNETIC [CR(C6H6)(2)](+) IN AN ORGANIC ANION FRAMEWORK VIA CH-CENTER-DOT-CENTER-DOT-CENTER-DOT-O HYDROGEN-BONDS
BRAGA, D
GREPIONI, F
BYRNE, JJ
WOLF, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) : 1023 - 1024
[9] Moulding a honeycomb framework around [Co(eta(5)-C5H5)(2)](+) via charge-assisted C-H center dot center dot center dot O hydrogen bonds
Braga, D
Angeloni, A
Grepioni, F
Tagliavini, E
[J]. CHEMICAL COMMUNICATIONS, 1997, (15) : 1447 - 1448
[10] Braga D, 1997, ORGANOMETALLICS, V16, P5478

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