Efficient synthesis of water-soluble calixarenes using click chemistry

被引：182

作者：

Ryu, EH ^{[1
]}

Zhao, Y ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 06期

关键词：

D O I：

10.1021/ol047468h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several water-soluble calix[4]arenes were synthesized via Huisgen 1,3-dipolar cycloaddition between azides and alkynes. Cationic, anionic, and nonionic calixarenes were prepared from a common azidocalixarene intermediate. Azidocalixarenes performed better than alkynylcalixarenes as precursors. The aggregation behavior of the water-soluble calixarenes was studied by H-1 NMR spectroscopy.

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页码：1035 / 1037

页数：3

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